Dr. Thomas E. Bitterwolf

Publications

60. "Tricarbonylchromium complexes of Centropolyindanes", T. E. Bitterwolf, A. Ceccon, A. Gambaro, P. Ganis, D. Kuck, F. Manoli, A. L. Rheingold, G. Valle, and A. Venzo, submitted to J. Chem. Soc., Dalton, 1996.
59. "Ligand Exchange Photochemistry of M2(CO)4(ľ- 5, 5-C5H4CH2C5H4) (M = Fe or Ru) and Thermal Acetylene Exchange of Ru2(CO)(ľ-CO)[ľ- 1: 1-(C6H5)2C2](ľ- 5, 5-C5H4CH2C5H4). The Molecular Structures of Ru2(CO)( -C6H5)(ľ-CO)[ľ-P(C6H5)2](ľ- 5, 5-C5H4CH2C5H4) and Ru2(CO)(ľ-CO)[ľ- 1, 3-C6H5C=C(C6H5)O](ľ- 5, 5-C5H4CH2C5H4)," T. E. Bitterwolf and J. L. Haener, J. E. Shade, A. L. Rheingold and G. P.A. Yap, In Press, J. Organometallic Chemistry, 1996.
58. "Photochemical Studies of Mono and Bimetallic Cyclopentadienyl Molybdenum Allyl Compounds. Molecular Structures of [Mo(CO)2( 3-C3H5)]2[ 5, 5-C5H4C(CH3)2C5H4] and [Mo(CO)3][Mo(CO)2( 3- C3H5)][ 5, 5: 1-C5H4C(CH3)2C5H3]," T. E. Bitterwolf, J. T. Bays, and A. A. Saygh, J. E. Shade, A. L. Rheingold, G. P. A. Yap, and L. M. Lable-Sands, Submitted Organometallics, 1996.
57. "Ring Functionalized Cyclopentadienyl Derivatives of Niobium and Tantalum. Molecular Structures of ( 5-C5H4-CO2CH3)M(CO)4 where M = Nb and Ta and ( 5-C5H4- CO2CH2C6H5)Nb(CO)4." T. E. Bitterwolf and S. Gallagher, A. L. Rheingold and G. P. A. Yap, Submitted to J. Organometallic Chemistry, 1996.
56 ."Two Momomeric Ruthenium Complexes Containing Bidentate Bis(diphenylphosphino)Ligands", W. H. Pearson, J. E. Shade, J. E. Brown, and T. E. Bitterwolf, Acta Cryst. C, 1996, C52, 1106.
55. "Photoinduced rearrangements of ring-coupled bis(cyclopentadienylrutheniumdicarbonyl) compounds of the form Ru2(CO)4( 5, 5-C5H4-L-C5H4), where L = CH2, (CH3)2C, C2H4 and (CH3)2Si-," T. E. Bitterwolf, J. E. Shade, J. A. Hansen, and A. L. Rheingold, J. Organometal. Chem., 1996, 514, 13.
54. "Synthesis of mono- and bimetallic ruthenium carbonyl compounds from ring-coupled bis(cyclopentadienylthallium) reagents," T. E. Bitterwolf, M. B. Leonard, P. A. Horine, J. E. Shade, A. L. Rheingold, D. J. Staley, and G. P. A. Yap, J. Organometal. Chem. 1996, 512, 11.
53. "Convergent Synthesis of Heterobimetallic Compounds," T.E. Bitterwolf and S. Everly, J. Organometal. Chem., in press, 1996.
52. "Photochemical Reimer-Tieman Reactions of ( 5-C5H5)2Fe2(CO)2( -DPPM) and ( 5- C5H5)2Fe2(CO)2( -DPPE). The Molecular Structures of ( 5-C5H5)2Fe2(CO)2( -DPPM) and ( 5- C5H5)( 5-C5H4CHO)Fe2(CO)2( -DPPM)," T.E. Bitterwolf, J.E. Shade, J.E. Brown, and
51. "Photolysis of [ClRh(CO)2]2 in Inert Gas and Nujol Matrices," T.E. Bitterwolf, K.A. Lott, and A.J. Rest, submitted to J. Organometal. Chem, 1996.
50. "Stable zwitterions of indenyl and fluorenyl Cp*Ru (eta-6-arene) complexes", Wheeler, D.E.; Bitterwolf, T.E., Inorg. Chim. Acta, 205 (1993), 123-127.
49. "Binuclear Fulvalene and Bis(cyclopentadienyl)methane Halfsandwich Complexes of Manganese and Rhenium containing tetrahydrothiophene Ligands. X-ray Structure Analysis of {(CO)2Mn[C5H4-C5H4]Mn(CO)2}- -SC4H8," T.E. Bitterwolf, M. Herberhold, M. Biersack, and A.L. Rheingold, Z. Naturforsch, 48b (1993)161 - 170.
48. "A Facile Synthetic Route to ( 5-Benzoylcyclopentadienyl)metal compounds," T.E. Bitterwolf, S.S. Jones, and M.D. Rausch, J. Organometallic Chem., 450(1993)27 - 31.
47. "Chromium Tricarbonyl Derivatives of Hantzsch Esters Posess Robust Calcium Antagonist Activity", T.E. Bitterwolf, N.R. Natale, T.L. Hubler, S.B. Meikrantz, and D.J. Triggle, J. Med. Chem., 35(1992)1165 - 68.
46. "Resolution of Racemic Mixtures of Chiral Arenechromiumtricarbonyl Complexes Using a Bakerbond Chiralcel HPLC Column," T.E. Bitterwolf and T.L. Hubler, J. Organometal. Chem., 487 (1995) 119.
45. "Synthesis and Chemistry of 1-Acetyl, 2-Methylsubstituted Cyclopentadienyl Thallium and its Chiral Manganese and Rhodium Carbonyl Derivatives. The Molecular Structure of [1-CH3CO- , 2-CH3H5H3]Rh(CO)pP(C6H5)3]", T.E. Bitterwolf, T.L. Hubler, and A.L
44. "Wittig and Reformatsky Chemistry of the Formyl and Acetyl Derivatives of (C6H6)Cr(CO)3, (C5H5)Mn(CO)3, and (C5H5)Re(CO)3", T.E. Bitterwolf and Xuezhen Dai, J. Organometal. Chem., 440(1992)103 - 112.
43. "Synthesis of Tetrahydrofurfurylcyclopentadiene and its Thallium, Manganese, and Rhodium Complexes and the Low Temperature Matrix Photolysis of the Manganese Complex", T.E. Bitterwolf, K.A. Lott, and A.J. Rest, J. Organometal. Chem., 1991, 408, 137
42. "Class II Mixed-Valent Complexes from Oxidation of Doubly-Linked (Arene) Chromium Compounds," T.E. Bitterwolf, N. van Order, Jr. D.T. Pierce, W.E. Geiger, A.L. Rheingold, and N.D. Chasteen, Organometallics, 1991, 10, 2403.
41. "Synthesis and Structure of Tricarbonyl Mono-, Bis- and Tris Complexes of 10- Methyltribenzotriquinacene", T.E. Bitterwolf, A. Ceccon, A. Gambaro, F. Manoli, A. Venzo, D. Kuck, P. Ganis, and G. Valle, J. Chem. Soc., Perkins 2, 1991, 233.
40. "Photolysis of Group VI Metal Carbonyls, (C6H6)Cr(CO)3, (C5H5)Mn(CO)3, (CH3C5H4)Mn(CO)3, and (C5H5)Re(CO)3 in Nujol at 77 K", T.E. Bitterwolf, K.A. Lott, A.J. Rest, and J. Mascetti, J. Organometal. Chem., 419(1991)113 - 126.
39. "Separation of Racemic Mixtures of Organometallic Complexes Using Chiral Solid Supports", T.E. Bitterwolf, T.L. Hubler, and R. Todime, J. Macromol. Sci., 1990, A27, 1439.
38. "The Addition of Halogenocarbons to Alkenes in the Presence of [Mo2(CO)4(C5R5)2](R = H, Me), [Mo2(CO)6(C5H5)2] and [{Mo(CO)3(C5H4}2CH2]", T.E. Bitterwolf, R. Davis, N.N.S. Khazal, J. Organometallic Chem., 1990, 397, 51.
37. "Photochemistry of Some Dinuclear Molybdenum and Tungsten Cyclopentadienyl Carbonyl Complexes in Frozen Gas Matrices at ca 12K: Infrared Spectroscopic Evidence for Carbon Monoxide Ejection as a Primary Photoprocess", T.E. Bitterwolf, M.L. Baker, P.
36. "The Addition of Halogenocarbons to Alkenes in the Presence of [Fe2(CO)4(C5H5)2] and Related Compounds", T.E. Bitterwolf, R. Davis, J.L.A. Durrant and N.M.S. Khazaal, J. Organometallic Chemistry, 1990, 386, 229.
35. "Photochemistry of Some Manganese and Chromium Dinuclear Metal Carbonyl Complexes in Frozen Gas Matrices at ca 12K", T.E. Bitterwolf, P.E. Bloyce, A.J. Rest, N.J. Fitzpatrick, J. Chem. Soc, Dalton Trans., 1989, 833.
34. "Synthesis of 1,4-bis(cyclopentadienylthallium)-1,4-butadione and Its Application to the Synthesis of Dinuclear Organometallic Complexes", T.E. Bitterwolf, J. Organometal. Chem., 1990, 386, 9.
33. "Synthesis of Acetyl, Formyl, and Alkylcarboxylcyclopentadienylthallium Reagents and Their Application in Organometallic Synthesis", T.E. Bitterwolf, S.J. Jones, M.D. Rausch, and A.L. Rheingold, J. Organometal. Chem., 1990, 396, 279.
32. "Energy Barriers to Ring Oscillations in Dinuclear Complexes with Methylene Coupled Cyclopentadienyl Rings", T.E. Bitterwolf, A. Ceccon, A. Gambaro, and F. Gottardi, Organometallics, 1991, 10, 1416.
31. "Photochemical Studies of Iron and Ruthenium Dimers in Inert Gas Matrices at 12oK", T.E. Bitterwolf, A.K. Campen, P. Bloyce, R. Hooker, A.J. Rest, J.E. Shade, J. Chem. Soc., Dalton, 1990, 2833.
30. "Synthesis of New Dinuclear Ruthenium Complexes Containing Parallel Bridging Acetylenes and their Thermal Reactions with Cyclic Arsines to Yield u-Arsinidene Complexes". T.E. Bitterwolf, A.L. DiMaio, and A.L. Rheingold, Organometallics, 1990, 3, 5
29. "Synthesis, Oxidation and Acid Reactions of Dinuclear Cyclopentadienyl Rhodium Carbonyl Phosphine Compounds", T.E. Bitterwolf, C. Spink, and M.D. Rausch, J. Organometal. Chem., 1989, 363, 189.
28. "Synthesis and Chemistry of Bis(cyclopentadienylmetaltricarbonyl)methane Derivatives of Molybdenum and Tungsten." T.E. Bitterwolf and A.L. Rheingold, In Press, Organometallics, 1991.
27. "Effects of Ligand and Metal on the Reductive Elimination of Dihydrogen by Dinuclear Complexes of Chromium and Manganese". T.E. Bitterwolf and K.S. Raghuveer, Inorg. Chem. Acta, 1990, 172, 59.
26. "Formation and Synthetic Utility of Benzyl- and Phenylcyclopentadienyl-thallium", T.E. Bitterwolf, M.D. Rausch, and P. Singh, J. Organometal. Chem., 1988, 352, 273.
25. "Correlation of 31P Chemical Shifts and Carbonyl Stretching Force Constants with Substituent Constants for a Series of Ring-Substituted Arene Chromium Dicarbonyl Triphenylphosphine Complexes", T.E. Bitterwolf, Polyhedron, 1988, 7, 1377.
24. "Conformation and Stabilization of the Bis(chromiumtricarbonyl)fluorenyl Anion", T.E. Bitterwolf, J.E. Shade, A. Ceccon, A. Gambaro, A. Venzo, J. Organometal. Chem., 1988, 349, 315.
23. "Formation of Dinuclear Ruthenium Hydride Species During Photolysis of Bis(dicarbonyl)(n5-cyclopentadienyl)ruthenium and its Derivatives", T.E. Bitterwolf, J.A. Hansen, and A.L. Rheingold, Submitted to Organometallics, 1988. Revised manuscript in
22. "Effect of a Series of Phosphine and Phosphite Ligands on the Taft Substituent Constants of Arenechromiumcarbonyl and Cyclopentadienyl- manganesecarbonyl Complexes", T.E. Bitterwolf, Polyhedron, 1988, 5, 409.
21. "Dimerization of a 17-Electron Cation Radical by Formation of a Rhodium-Rhodium Bond", T.E. Bitterwolf, E. Fonseca, W.E. Geiger, and A.L. Rheingold, Organometallics, 1988, 7, 567.
20. "Synthesis and Molecular Structure of a Dirhodium Complex of Bis(cyclo- pentadienyl)methane containing a u-Methylidene Bridge: CH2[C5H4Rh(CO)]2-u-CH2", T.E. Bitterwolf and A.L. Rheingold, Organometallics, 1987, 6, 2138.
19. "Metal-Stabilized Carbanions IX: The Influence of Metal Basicity on the n6-n5 Haptotropic Equilibrium of (Fluorenyl)-Cr(CO)2L Anions", T.E. Bitterwolf, J.E. Shade, A. Ceccon, A. Gambaro, A. Venzo, V. Lucchini, J. Organometal. Chem., 1987, 327, 55
18. "Mixed-Valent Cations of Dinuclear Chromium Aryl Complexes: Electrochemical, Spectroscopic, and Structural Considerations", N. Van Order, W.E. Geiger, T.E. Bitterwolf, and A.L. Rheingold, J. Amer. Chem. Soc., 1987, 109, 5680.
17. "Synthesis and Conformations of Chromium Tricarbonyl Substituted Diarenes", T.E. Bitterwolf, R. Herzog and P.D. Rockswold, J. Organometal. Chem., 1987, 320, 197.
16. "Reactions of Sulfur Dioxide with New Dinuclear Rhodium Compounds", T.E. Bitterwolf, J. Organometal. Chem., 1987, 320, 121.
15. "Bis(cyclopentadienylthallium)methane: A Versatile Intermediate for the Synthesis of Dinuclear Cyclopentadienylmetal Carbonyl Complexes", T.E. Bitterwolf, J. Organometal. Chem., 1986, 312, 197.
14. "Protonation and Dimerization Reactions of Cyclopentadienylrhodium-carbonylphosphine and Phosphite Derivatives", T.E. Bitterwolf, Inorg. Chem. Acta, 1986, 122, 175.
13. "Metallocene Basicity VIII: Protonation of Bridge Substituted Ferroceno-phanes in Strong Acid Media", T.E. Bitterwolf, Inorg. Chem. Acta, 1986, 117, 55.
12. "Polymer Bound Bimetallic Complexes as Surface Reactants on Semiconductor Electrodes" T.E. Bitterwolf, Organometallic and Inorganic Polymers (C. Carraher, J. Sheats and C. Pittman, eds.) Plenum Press, 1985.
11. "Metallocene Basicity VII: Protonation of Ring Substituted Ferrocenophanes", T.E. Bitterwolf and M.J. Golightly, Inorg. Chem. Acta, 1984, 84, 153.
10. "Reductive Elimination of Dihydrogen from Arenechromium Dimers", T.E. Bitterwolf, J. Organometal. Chem., 1983, 252, 305.
9. "Taft Substituent Constants for Arene Chromium Dicarbonyl Phosphine and Arsine Derivatives", T.E. Bitterwolf, Polyhedron, 1983, 2, 675.
8. "Metallocene Basicity VI: Electronic Spectra of Protonated Ferrocenes", T.E. Bitterwolf, Tetrahedron Letters, 1981, 22, 2627.
7. "Metallocene Basicity V: Protonation of Ferrocenophanes in Strong and Weak Acids", T.E. Bitterwolf and A.C. Ling, J. Organometal. Chem., 1981, 215, 77.
6. "Metallocene Basicity IV: Conformational and Electronic Behavior of Some Protonated Ferrocenes" T.E. Bitterwolf and A.C. Ling, J. Organometal. Chem., 1977, 141, 355.
5. "Preparation of Isomerically Pure Stannyl Ferrocenes" T.E. Bitterwolf and A.C. Ling, Synth. React. Inorg. Metal Org. Chem., 1977, 7, 367.
4. "Metallocene Basicity III: Protonation of Compounds Containing Two Ferrocenly Moieties" T.E. Bitterwolf and A.C. Ling, J. Organometal. Chem., 1973, 57, C15.
3. "Metallocene Basicity II: Reaction of the Ferrocenonium Cation with O2 and SO2", T.E. Bitterwolf and A.C. Ling, J. Organometal. Chem., 1972, 40, C29.
2. "Metallocene Basicity I: Ring Tilt and Restricted Rotation in Protonated Ferrocenes", T.E. Bitterwolf and A.C. Ling, J. Organometal. Chem., 1972, 40, 197.
1. "Temperature Dependence of the Hammett Reaction Constant", T.E.
Bitterwolf, R.E. Linder, and A.C. Ling, J. Chem. Soc., B, 1970, 864.

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Bob Tolbert (tolbert@cobalt.chem.uidaho.edu)